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Molality - Boiling Point Elevation:    


In dilute solutions, the elevation of the boiling point is directly proportional to the number of solute molecules (or moles) in a given weight of solvent.  The effect of a nonelectrolyte dissolved in water can be calculated by:

kb x m  =  DTb        (kb  =  molal B.P. constant for H2O  =  )

 (m  =  molality of the solution)

Then, the boiling point of the solution can be calculated by:  Boiling point of solvent  +  DTb

   Example:  What is the boiling temperature of a solution containing 30.0 g of a nonelectrolyte (MM = 180 g/mol) dissolved in 100 g (0.100 kg) of water?

kb x m  =  x 167 m  =  0.857 oC  =  DTb  

B.P. of water  +  DTb  =  100.000 oC (at 1 atm)  +  0.857  =  100.857 oC

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