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The
Periodic Table
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“As new elements were discovered, their
atomic masses were determined, and the way each reacted with other substances
was studied. Chemists began to notice
families of elements that showed similar behavior. As early as 1829 Johan Döbereiner (1780-1849) had
introduced the idea of triads of elements (groups of three): thus lithium, sodium, and potassium, all
similar metals, formed one group, and they tended to behave in the same way. The Russian chemist Dmitri Mendeleyev
(1834-1907) observed that elements listed in order of atomic mass showed
regularly (or periodically) repeating properties. He announced his Periodic Law in 1869 and
published a list of known elements in a tabular form. He had the courage to leave gaps where
the Periodic Law did not seen to fit, predicting that new elements would be
discovered to fill them.”
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The
modern periodic table has evolved through a long history of attempts by
chemists to arrange the elements according to their properties as an aid in
predicting chemical behavior.
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Johannes
Döbereiner
in circa 1800 noticed that many of the known elements could be grouped in triads,
sets of three elements that have similar properties.
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In the
early 1800's Dobereiner noted that similar elements often had relative atomic
masses, and DeChancourtois made a cylindrical table of elements to display
the periodic reoccurrence of properties.
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By the
mid-nineteenth century, John Newlands hypothesized that the chemistry of the
elements might be related to their masses and arranged the known elements in
order of increasing atomic mass and found
that every seventh element had similar properties. Newlands suggested that the elements could
be classified into octaves, corresponding to the horizontal rows in
the main group elements, but this did not seem to work for elements heavier
than calcium.
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Cannizaro
determined atomic weights for the 60 or so elements known in the 1860s, then
a table was arranged by Newlands, with the elements given a number in series
in order of their atomic weights, beginning with Hydrogen.
This made evident that "the eighth element, starting from a given one,
is a kind of repetition of the first", which Newlands called the Law of
Octaves.
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Both
Meyer and Mendeleyev constructed periodic tables independently that are
credited as being the basis of the modern table. Meyer was more impressed by
the periodicity of physical properties, while Mendeleyev was more interested
in the chemical properties.
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“No one
foresaw the discovery of an entirely new group of elements in the
1890’s. They were added as a separate
column. The periodic table did not
immediately have an impact on chemical theory until the discovery of missing
elements.”
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The
periodic table achieved its modern form through the work of Julius Meyer and
Dimitri Mendeleev, who focused on the relationships between atomic mass and
various chemical properties.
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Mendeleyev
published his periodic table & law in 1869 and forecast the properties of
missing elements, and chemists began to appreciate it when the discovery of
elements predicted by the table took place. Periodic tables have always been
related to the way scientists thought about the shape and structure of the
atom, and has changed accordingly.
Dimitri Mendeleyev
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"...if all the elements be arranged
in order of their atomic weights a periodic repetition of properties is
obtained." - Mendeleyev
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Mendeleev
had gained considerable notoriety by boldly predicting chemical properties of
certain undiscovered elements.
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In 1869,
they independently proposed essentially identical arrangements of the
elements. The periodic law appears to
have been discovered by at least six people independently within the one
decade - Mendeleyev, Lothar Meyer, Hinrichs, Odling, Newlands, and De
Chancourtois.
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Meyer
aligned the elements according to periodic variations in simple atomic
properties such as atomic volume, which he obtained by dividing the atomic
mass (molar mass) in grams per mole by the density of the element in grams
per cubic centimeter:
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molar mass (g/mol)
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density (g/cm3) = molar volume (cm3/mol)
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The
`modern' periodic table is very much like a later table by Meyer, arranged,
as was Mendeleyev's, according to the size of the atomic weight, but with
Group 0 added by Ramsay. Later, the table was reordered by Mosely according
to atomic numbers (nuclear charge) rather than by weight.
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-Eyewitness
Science “Chemistry” , Dr. Ann Newmark, DK Publishing, Inc., 1993, pg 23
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Newlands
(English chemist) idea was rejected by the scientific community for ~20
years. In 1887, Newlands accepted the
Davy Medal from the Royal Society of Great Britain.
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1800 Only 30 elements had been isolated and
identified.
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1870 60 known elements
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Lothar
Meyer (German chemist)
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