Precipitation Reactions:
Precipitation is the formation of a solid as
a result of the combining of solutions. This is a chemical reaction in
which a product is formed which has low solubility in water.
Example:
Silver nitrate solution + sodium chloride solution combine to form
silver chloride precipitate + sodium nitrate solution.
AgNO3(aq) +
NaCl(aq) --> AgCl(s) +
NaNO3(aq)
REACTANTS Aqueous solutions will dissociate in solution: AgNO3(aq)
--> Ag1+(aq) + NO31-(aq)
NaCl(aq) --> Na1+(aq) + Cl1-(aq)
PRODUCTS Using a solubility table, it
could be determined that silver chloride will form the precipitate AgCl(s) and silver
nitrate will remain in solution. NaNO3(aq)
--> Na1+(aq)
+ NO31-(aq)
Ag1+(aq)
+ NO31-(aq)
+ Na1+(aq) + Cl1-(aq)
--> AgCl(s) + Na1+(aq)
+ NO31-(aq)
[This is called an ionic equation]
Ag1+(aq)
+ Cl1-(aq) --> AgCl(s)
[This is called the net ionic
equation]
This is an equation showing the only
reaction that is taking place, and is called the net
ionic reaction. The species represented are called the
predominant reacting species.
Those ions not taking an active part in
the reaction are called spectator ions (Na+
and Cl-).
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